ORCID Identifier(s)

0000-0002-2868-6126

Graduation Semester and Year

2020

Language

English

Document Type

Dissertation

Degree Name

Doctor of Philosophy in Materials Science and Engineering

Department

Materials Science and Engineering

First Advisor

Kyungsuk Yum

Abstract

Shape-changing materials that can adopt programmable 3-dimensional (3D) shapes offer promise for a wide range of applications. Form the formation of the leaves and flowers to the shaping of complex organs, the analogues of such shape-morphing 3D surfaces are abundant in nature. However, since the formation of such surfaces in biological systems is fundamentally different from that of human-made materials, replicating their complex morphologies, movements, and thereby functions remains a challenge. Inspired by living organisms, we introduce an approach, called digital light 4D printing (DL4P), that encodes thermosensitive 2D hydrogels with a specific pattern of network density and thus temperature-induced growth (expansion and contraction) to create 3D structures with programmed shapes and motions. 3D self-shaping happens readily upon the introduction of the programmed 2D hydrogels into water medium, where programmed non-uniform in-plane growth defines a new metric tensor (target metric) for the surface, which causes a controlled out-of-plane buckling and results in a specific three-dimensional shape. A theoretical platform was introduced for axisymmetric 3D shapes, predicting how a target metric translates to a 3D shape and vice versa. We next introduced modular-based design rules for making complex 3D structures and addressed control of the direction of deformation in non 2 Euclidean systems. By controlling the spatial rates of shape transformations, we created 3D structures with complex programmed sequential motions similar to living organisms. To broaden the application of our method beyond soft-materials, we established a thermal/chemical shape stabilization process to achieve robust air-stable 3D surfaces in the ambient environment. Unlike traditional layer-by-layer additive manufacturing, our controlled out-of-plane deformation mechanism allows the creation of 3D structures in a short amount of time from a single layer material. The digital patterning used in this method offers simultaneous printing of 2D materials encoded with custom-designed metrics, rendering it scalable for creating diverse 3D shapes.

Keywords

4D Printing, Shape-morphing

Disciplines

Engineering | Materials Science and Engineering

Comments

Degree granted by The University of Texas at Arlington

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