ORCID Identifier(s)

0000-0002-7842-8264

Graduation Semester and Year

Spring 2025

Language

English

Document Type

Dissertation

Degree Name

Doctor of Philosophy in Quantitative Biology

Department

Biology

First Advisor

Dr. Woo-Suk Chang

Second Advisor

Dr. Alison Ravenscraft

Third Advisor

Dr. Luke O. Frishkoff

Fourth Advisor

Dr. Dylan B. Parks

Abstract

The increasing global regulations of glyphosate due to its possible carcinogenicity and environmental hazards have necessitated the search for alternative herbicides. Glufosinate-ammonium offers a sustainable attribute due to its low toxicity and limited reported herbicide resistance cases. Despite its increasing agricultural importance, very limited studies are done on its environmental impact, especially on the soil systems. This thesis examines the ecological behavior of glufosinate in soil, precisely focusing on its effect on the dynamics of soil microbiome and the potential use of Bradyrhizobium japonicum USDA110 for bioremediation by reversing the effect of microbial dysbiosis. A series of 30-day mesocosm studies were performed using different concentrations of glufosinate (43 and 86 fl. oz./A) to assess its impact on microbial diversity and pesticide degradation. High-throughput 16S rRNA gene sequencing shows a dose-dependent shift in soil microbiome towards glufosinate-tolerant taxa, notably Firmicutes, along with decreased species richness and evenness. Residual glufosinate measurement shows faster reduction in the two-time treatment group. This result complements the study from the metagenomics, suggesting adaptive enrichment of species, such as Bacillus and Pseudomonas, that are well known for glufosinate degradation. Weighted Gene Co-Expression Network Analysis (WGCNA) and co-occurrence network modeling show Pseudomonas, Hyphomicrobium, and Streptomyces as significant genera potentially contributing to accelerated glufosinate degradation.

A parallel experiment suggests the bioremediation capabilities of B. japonicum USDA110 in the presence of glufosinate. Additionally, a comparative study was performed to see the effect of microbial activity on glufosinate reduction in soil by autoclaving soil. The results indicate improved glufosinate degradation and microbial stability in the soil inoculated with the bacteria. Furthermore, inoculation helped with the preservation of phylogenetic diversity and Proteobacteria abundance. This suggests improved stability and partial reversal of glufosinate-induced microbial dysbiosis.

Keywords

Pesticide, Glufosinate, Soil Microbiome, Bradyrhizobium japonicum USDA110, Bioremediation, Network Analysis

Disciplines

Environmental Microbiology and Microbial Ecology

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